College of Engineering
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Item THE EFFECTS OF INHIBITION OF FERN EXTRACTS ON THE ALKALINE AND ACID CORROSION OF ALUMINIUM ALLOY(RASAYANJ. Chem. Vol. 14 | No. 4, 2021-10) Udonne, J. D.; Efeovbokhan, V. E.; Medaiyese, F.; Akinyemi, O. P.; Oladimeji, Temitayo EThe deterioration behavior of aluminum alloy in 1M Hydrochloric acid and 1M Sodium hydroxide solution in fern extract was investigated using a weight loss technique. Aluminum alloy coupons of dimension 4 by 4 cm were immersed in test solutions of uninhibited acid and alkaline solutions, and also those containing the extract concentrations of 1, 2, 3, 4, and 5 g/l at ambient temperature for 168 hours. The test results show that the fern extract exhibited lower inhibitive properties in the alkaline than in the acidic medium. The observed adsorption characteristics were best described using Langmuir isotherm. The thermodynamic properties obtained were best described by physical adsorption mechanisms.Item Impact assessment of particulate pollution on maternal mortality in Nigeria(Scientific Reports, 2022) Emetere, M. E.; Oladimeji, Temitayo EItem Investigation of Some Gaseous and Trace Metal Emissions With Their Emission Factors From Various Brands of Mosquito Coils Used in Nigeria(Environmental Health Insights Volume 16, 2022) Elehinafe, Francis B; Okedere, Oyetunji B; Oladimeji, Temitayo E; Anabui, Sarah O.Mosquito coils of various brands are frequently burnt in indoor environments to drive away mosquitoes—the vector for malaria parasite in regions where the disease is endemic. Emissions from the coils could be a source of indoor air pollution. In this study, various brands of mosquito coils obtained from retail shops in Lagos, Nigeria were burnt in an environmental test box with a view to characterizing carbon monoxide (CO), nitric oxide (NO), and nitrogen dioxide (NO2) in the gaseous emissions as well as elemental concentrations of the ash. Emission characterization achieved with the RAS1700 bio-gas analyzer while AAS was adopted for elemental analysis of the mosquito coil ashes. The emission factor of CO, NO and NO2 from the coil samples ranged between 0.00138 to 0.26277 μg/m3, 0.0002 to 0.00454 μg/m3, and 0.000074 to 0.00714 μg/m3, respectively. These values were found to be lower than permissible indoor levels recommended by NIOSH. The range of concen trations of Pb, Zn, Cd, Cr, Cu, As, Hg, Fe in the coil ashes from all the brands were 0.02 to 0.04 mg/g, 0.011 to 0.02 mg/g, 0.001 to 0.003 mg/g, 0.004 to 0.008 mg/g, 0.004 to 0.006 mg/g, 0.0001 to 0.0004 mg/g, 0.001 to 0.003 mg/g, and 0.124 to 0.14 mg/g, respectively. Although, the con centrations of the pollutants obtained in this study are within the recommended limits, prolong exposure could trigger chronic disease conditions. Adequate ventilation of indoor environments or utilization of mosquito nets in place of coils could be considered.Item Data on the corrosion Inhibition Property of Rosemary on High Carbon Steel in dilute sulphuric acid, citric acid and sodium chloride solution(Chemical Data Collections (Chemical Data Collections ), 2021) Odunlami, Olayemi; Loto, R. T.; Fajobi, Michael Ayobami; Olomukoro, O. T.; Akande, I. G.; Oke, M. A.; Oladimeji, Temitayo EThe data of electrochemical analysis of Rosmarinus officinalis (RO) essential oil effect on high carbon steel (HCS) in three different corrosive environment of sodium chloride, sul- phuric acid and citric acid solution was achieved via weight loss method. Results revealed that Rosmarinus officinalis (RO) organic compound performed excellent well on high carbon steel samples with the optimum inhibition value occurring in NaCl solution with 97.87% after 504 h. The corrosion rate values were significantly high at 0 ml RO organic com- pound for all the three (3) corrosive environments as the time of immersion moves down to 504 h. It was clearly observed that time of immersion and concentrations of RO are the main determinant factor for the excellent adsorption performance of RO organic compound within the range of 504 h. Also, Rosmarinus officinalis (RO) organic compound retarded the severe corrosion rate of high carbon steel samples in other corrosive solutions with aver- age range inhibition values between 40 and 78% after 504 h.Item A Review of Corrosion Threat in Marine Industry(Key Engineering Materials, 2025) Odunlami, Olayemi; Fajobi, Muyiwa; Nnaji, Uchenna; Uriah, Abigail; Gawati, Tomisin; Oladimeji, Temitayo E; Adisa, HassanCorrosion poses a significant challenge in the marine industry, leading to the deterioration of equipment and structures, and resulting in substantial costs for its management and control. This comprehensive review focuses on how metal structures in marine environments, such as ships, are affected by corrosion. It explores different forms of corrosion and strategies to prevent it, particularly in the context of marine vessels. The review includes real-world examples of ships, highlights the financial impact of corrosion in the marine sector, and examines the factors contributing to its occurrence. Corrosion prevents a significant issue for marine vessels and related equipment due to the potential damage to the metal they are constructed from. However, there are effective methods to mitigate this problem, such as employing corrosion-inhibiting substances and selecting appropriate materials. The susceptibility of materials to corrosion varies depending on their composition, resulting in either widespread deterioration or localized damages. By thoroughly examining the corrosion challenge within the maritime industry, this review provides insights into managing and mitigating its effects more efficiently.Item Demulsification of a Nigerian crude emulsion using ethoxylated-resoles and their xylene modified blends(International Conference on Recent Trends in Applied Research, 2021) Efeovbokhan, Vincent E.; Chibuzor, Chukwuebuka C.; Babalola, Rasheed; Abatan, Olubunmi G; Oladimeji, Temitayo EDemulsification is a method used to reduce or disrupt the water - crude oil emulsion system without uttering the initial composition of the crude oil. This process is done by the introduction of chemicals called demulsifiers, which break the emulsion into aqueous and organic phases. In this study, the demulsifier formulated was the base-catalyzed phenol formaldehyde resin known as the resoles, with the ratios of phenol to formaldehyde, varied between 1.0:1.2 and 1.0:2.0. The different samples of resoles where then ethoxylated to make them more hydrophilic using different weights (10, 15 & 20 g) of polyethylene glycol (PEG). Screening of the ethoxylated demulsifiers was done using the established bottle test procedure, at 70 °C, the concentration of 50 ppm, and 20 minutes of residence or separation time, in order to select the most effective demulsifier, based on the amount of water removed from the emulsion. The best chemical-demulsifier produced was the ethoxylated resole, which was then blended with xylene at varying percentages (0, 20, 40, 50, and 80 % weight/weight) and was further screened, using the bottle test method. From the analysis, it was obtained that the most effective ethoxylate-xylene demulsifier blend was sample DR3, and made of formaldehyde to phenol ratio of 1.8:1, 20 g of PEG 400 blended with 20 % xylene. The demulsifier gave a water separation efficiency of 85.7 %, compared with the commercial demulsifier, which yielded 72.7 %. The result indicates the practical significance of solvent modified demulsifiers for separating crude oil emulsions in the petroleum industries.Item From origin to oversight: properties, impacts and management of heavy metals(Discover Applied Sciences, 2025) Oladimeji, Temitayo E; Oyedemi, Melody O; Odunfa, Moradeyo K; Agboola, Oluranti; Adeoye, John B; Oke, Michael A.; Akindele, Olubukola O.Heavy metals, derived from both natural processes (e.g., rock weathering) and anthropogenic activities (e.g., industrial emissions, agricultural runoff), pose significant environmental and health risks due to their persistence and bioaccumulation in ecosystems. This review emphasizes the need for an in-depth examination of heavy metals, their sources, properties, toxicity, and management. The document also evaluates regulatory frameworks aimed at managing heavy metal contamination and highlights the need for innovative detection and regulation. It underscores the importance of future research and policy advancements to strengthen remediation efforts, safeguard public health, and promote sustainable environmental practiceItem Production of activated carbon from sawdust and its efficiency in the treatment of sewage water(Materials Science Forum, 2025) Oladimeji, Temitayo E; Olaniyan, Ifeoluwa F.; Emetere, Moses E.; Adeoye, John B.; Odunlami, Olayemi, A.; Abatan, Olubunmi G.The use of activated carbon for wastewater treatment has been established based on sustainability and cost. This study delves into the intricate process of producing activated carbon from cow and goat bones and explores the efficiency of this material in removing contaminants from distillery wastewater. The samples were carbonized at 700°C in a muffle furnace, then crushed in a mortar after cooling. The crushed samples were activated using 0.4M phosphoric acid for 24 hours and washed with distilled water, and finally oven dried. The elemental and microstructural was carried on the prepared activated carbon (AC) samples using X-ray Fluorescence (XRF) and Scanning Electron Microscopy (SEM). The heavy metals in the treated water were tested using Atomic Absorption Spectroscopy (AAS). The AC was used to treat waste water and factors on which adsorption depend, such as contact time (35 minutes and 60 minutes), adsorbent dosage (2.5g and 5g), and initial contaminant concentration (100% and 50%) were varied for each activated carbon sample (cow bone AC, goat bone AC, and a mixture of equal ratios of both). It was reported that activated carbon prepared from animal bones is rich in calcium. Also, chemical activation with phosphoric acid led to an increase in the external surface area of the particles with irregular cavities and pores. AC prepared from the mixture of cow and goat bones was most effective for distillery wastewater purification.Item Production of activated carbon from sawdust and its efficiency in the treatment of sewage water(Heliyon, 2021) Oladimeji, Temitayo E; Odunoye, Babatunde O.; Elehinafe, Francis. B; Obanla,, Oyinlola, R.; Odunlami, Olayemi, A.When water is contaminated and rendered unfit for drinking, it is regarded as waste, which leads to water pollution. Several works have been done to control water pollution, yet this topic is still a point of concern up to date. The study involves the production of activated carbon (AC) using sawdust to treat sewage water obtained from Covenant University. The following conditions were investigated; activation time and temperature, acti vating agent concentration, and impregnation time. The AC was characterized by measuring ash content, iodine value, moisture, and volatile matter content. The optimum activated carbon prepared in this study had iodine of 1628.95 mg/gm, while the minimum activated carbon had an iodine of 470.41 mg/gm. According to standard procedure, the sewage water sample was characterized physio-chemically before and after treatment using activated carbon as an adsorbent. The results obtained indicated considerable improvement in the quality of the water. When optimum activated carbon was used for treatment, pH value changed from 7.7 to 7.10, biochemical oxygen demand (BOD) was reduced from 288 mg/l to 20 mg/l and Total dissolved solids (TDS) reduced from 183.7 mg/l to 16.4 mg/l, Total suspended solids (TSS) reduced 232 mg/l to 15.7 mg/l. When minimum activated carbon was used for treatment, pH value changed from 7.7 to 7.60, BOD was reduced from 288 mg/l to 112.2 mg/ l, and TDS reduced from 232 mg/l to 174 mg/l, TSS reduced 183.7 mg/l to 103 mg/l. The results obtained led to the conclusion that the produced activated carbon effectively treats the above-stated water quality parameters.