Department of Chemical Engineering.
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Item Short review on the prospect of laser cladding for aluminum based alloys composite for automotive industries(RESEARCH ARTICLE, 2022-08) Agboola O.; Fayomi O. S. I.; Ayoola A.; Ayeni A. O.; Alagbe E. E.; Sadiku E. R.; Popoola P.Laser cladding is a growing technological method that utilizes a navigating high power laser for melting a small region of the substrate; it has a function of trapping and melting entering powder particles. Hence, the process leads to the development of a new stratum. Aluminum alloy Matrix composites afford properties suchlike high wear resistance, high tensile strength, lightweight; this composites is finding wide applications in automotive industry. This review presents a brief discussion on laser cladding for aluminum base alloys for automotive industry with emphasis on aluminum alloys matrix composite for automotive industry.Item Influence of synthetic carbon grade on the monomeric constitution of polyhydroxyalkanoate produced by Bacillus cereus AAR-1(2024) Akinwumi A. R.; Nwinyi O. C.; Ayeni A. O.; Mohan S. VenkataThree synthetic sucrose samples with varying manufacturing purity levels were selected as carbon substrates to synthesize diverse polyhydroxyalkanoates (PHAs) using a wild-type Bacillus cereus AAR-1. Comparative analyses of the extracted biopolymers were characterized using Fourier-transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (1H and 13C NMR), gas chromatography-mass spectrometry (GC-MS), Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), CHNS/O elemental analysis, and X-ray diffraction (XRD). The biopolymers identified include Poly(3-hydroxytetradecanoate) (P3HTD), Poly(3-hydroxybutyrate-co-2-hydroxytetradecanoate) [P(3HB-co-2HTD)], and Poly(3-hydroxybutyrate) (P3HB). The carbon content of the biopolymers ranged from 39-53%, with no nitrogen element detected. The thermal decomposition temperature of [P(3HB-co-2HTD)] was 279 °C, surpassing the corresponding values for the other two biopolymers. Notably, the homopolymer P3HTD exhibited an increased melting temperature of 172.4 °C and a reduced crystallinity percentage (Xc %= 20%), crucial properties for bioplastics and medical sector applications. The results suggest that different carbon purity grades influenced homopolymer accumulated in Bacillus cereus AAR-1.Item Gasific: A Python Tool for Biomass Gasification Process(Advanced Manufacturing in Biological, Petroleum, and Nanotechnology Processing, 2022-04-04) Oladokun O.; Nyakuma B.; Luing W. S.; Oladimeji E.; Abatan O.; Ayeni A. O.; Agboola O.; Ayoola A. A.; Ojewunmi M. O.; Efeovbokhan V. E.Biomass gasification and the production of syngas are important in the production of biohydrogen, a green fuel and an energy carrier for the fuel cell. The tool for the prediction of biohydrogen production from any biomass should be readily available to determine the viability of such biomass for gasification. The software implementing a robust gasification model is complex, proprietary, and expensive. In order to solve this problem, we developed Gasific, a software module for simple, free, and accurate biomass gasification product gas prediction. Gasific, implemented biomass gasification, stoichiometric equilibrium models, in Python and runs on a variety of platforms. We discussed the application of Gasific on biomass wastes, namely, Imperata cylindrica; the simulation shows good performance in predicting the gas composition product of gasification. The developed software and the code can be modified and applied to other scientific models and transform the models into software applications.Item A review on the sustainable energy generation from the pyrolysis of coconut biomass(Scientific African (Elsevier), 2021) Azeta Osarhiemhen; Ayeni A. O.; Agboola O.; Elehinafe Francis B.he negative impacts of the extraction and exploration of fossil fuel on the environment and its depletion that has led to environmental degradation have encouraged researchers, stakeholders, and the government to explore alternative and renewable energy sources such as lignocellulosic biomass. Biomass pyrolysis has proven to be a viable energy conversion process over the last decade due to its low carbon footprint on the environment. Pyrolytic products that are bio-char, bio-oil, and bio-gas have several applications and contribute to our society’s industrial, commercial, and economic growth. This paper reviews the different types of pyrolytic processes using coconut biomass as a feedstock while focusing on the biomass properties that make it useful for pyrolysis and the factors affecting the process.