Department of Chemical Engineering.
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Item Preparation and characterization of activated carbon from plantain peel and coconut shell using biological activators(International Conference on Engineering for Sustainable World, 2019) Efeovbokhan, V. E; Alagbe, E. E.; Odika, B.; Babalola, R.; Oladimeji, Temitayo E; Abatan, Olubunmi G.; Yusuf E. O.A concern over the toxicity of chemicals used during the activation stage in the preparation of activated carbon is beginning to gain attention. The study therefore looked into the possibility of using bio-activators (lemon juice and potash leached from the peel of unripe plantain) as activating chemicals, for environmentally friendly activated carbon. Coconut shell and the peel from unripe plantain were used as feedstock and pyrolyzed at 400 and 450 0c. An impregnation ratio of 0.25:1 was used while laboratory grade potassium hydroxide was used as a base activating agent as a control setup. Characterization of the activated carbon was carried out using parameters like bulk density and yield which were obtained using standard procedures. Results showed that activating carbon using bio-activators as activating agents had very good characteristics when compared with the control. Bio-activators are therefore recommended for the production of bio based activated carbon especially in the fields of medicine, food and pharmaceuticals. The effect of carbonization temperature on adsorption efficiency and pore structure were investigated using methylene blue as adsorbate and SEM respectivelyItem From origin to oversight: properties, impacts and management of heavy metals(Discover Applied Sciences, 2025) Oladimeji, Temitayo E; Oyedemi, Melody O; Odunfa, Moradeyo K; Agboola, Oluranti; Adeoye, John B; Oke, Michael A.; Akindele, Olubukola O.Heavy metals, derived from both natural processes (e.g., rock weathering) and anthropogenic activities (e.g., industrial emissions, agricultural runoff), pose significant environmental and health risks due to their persistence and bioaccumulation in ecosystems. This review emphasizes the need for an in-depth examination of heavy metals, their sources, properties, toxicity, and management. The document also evaluates regulatory frameworks aimed at managing heavy metal contamination and highlights the need for innovative detection and regulation. It underscores the importance of future research and policy advancements to strengthen remediation efforts, safeguard public health, and promote sustainable environmental practiceItem Production of activated carbon from sawdust and its efficiency in the treatment of sewage water(Materials Science Forum, 2025) Oladimeji, Temitayo E; Olaniyan, Ifeoluwa F.; Emetere, Moses E.; Adeoye, John B.; Odunlami, Olayemi, A.; Abatan, Olubunmi G.The use of activated carbon for wastewater treatment has been established based on sustainability and cost. This study delves into the intricate process of producing activated carbon from cow and goat bones and explores the efficiency of this material in removing contaminants from distillery wastewater. The samples were carbonized at 700°C in a muffle furnace, then crushed in a mortar after cooling. The crushed samples were activated using 0.4M phosphoric acid for 24 hours and washed with distilled water, and finally oven dried. The elemental and microstructural was carried on the prepared activated carbon (AC) samples using X-ray Fluorescence (XRF) and Scanning Electron Microscopy (SEM). The heavy metals in the treated water were tested using Atomic Absorption Spectroscopy (AAS). The AC was used to treat waste water and factors on which adsorption depend, such as contact time (35 minutes and 60 minutes), adsorbent dosage (2.5g and 5g), and initial contaminant concentration (100% and 50%) were varied for each activated carbon sample (cow bone AC, goat bone AC, and a mixture of equal ratios of both). It was reported that activated carbon prepared from animal bones is rich in calcium. Also, chemical activation with phosphoric acid led to an increase in the external surface area of the particles with irregular cavities and pores. AC prepared from the mixture of cow and goat bones was most effective for distillery wastewater purification.Item Production of activated carbon from sawdust and its efficiency in the treatment of sewage water(Heliyon, 2021) Oladimeji, Temitayo E; Odunoye, Babatunde O.; Elehinafe, Francis. B; Obanla,, Oyinlola, R.; Odunlami, Olayemi, A.When water is contaminated and rendered unfit for drinking, it is regarded as waste, which leads to water pollution. Several works have been done to control water pollution, yet this topic is still a point of concern up to date. The study involves the production of activated carbon (AC) using sawdust to treat sewage water obtained from Covenant University. The following conditions were investigated; activation time and temperature, acti vating agent concentration, and impregnation time. The AC was characterized by measuring ash content, iodine value, moisture, and volatile matter content. The optimum activated carbon prepared in this study had iodine of 1628.95 mg/gm, while the minimum activated carbon had an iodine of 470.41 mg/gm. According to standard procedure, the sewage water sample was characterized physio-chemically before and after treatment using activated carbon as an adsorbent. The results obtained indicated considerable improvement in the quality of the water. When optimum activated carbon was used for treatment, pH value changed from 7.7 to 7.10, biochemical oxygen demand (BOD) was reduced from 288 mg/l to 20 mg/l and Total dissolved solids (TDS) reduced from 183.7 mg/l to 16.4 mg/l, Total suspended solids (TSS) reduced 232 mg/l to 15.7 mg/l. When minimum activated carbon was used for treatment, pH value changed from 7.7 to 7.60, BOD was reduced from 288 mg/l to 112.2 mg/ l, and TDS reduced from 232 mg/l to 174 mg/l, TSS reduced 183.7 mg/l to 103 mg/l. The results obtained led to the conclusion that the produced activated carbon effectively treats the above-stated water quality parameters.Item Industrial- and automotive-used lubricating oils recycling cum acidic sludge treatment(Springer, 2019) Oladimeji, Temitayo E; Oguntuashe, Kehinde M.; Emetere, Moses E.; Efeovbokhan, Vincent E.; Odunlami, Olayemi A.; Obanla, Oyinlola R.Increased rise of industries and car usage in Nigeria and urban development is exponentially on the increase giving rise to multiple waste generation. Evaluation of the different recycling processes showed that acid-clay process has the highest environmental risk as well as the lowest cost; hence, this work added a treatment method for the slurry produced after treatment with acid-clay method, thereby reducing the environmental concern caused by acid and acid sludge formed in the process. The acid ratio was varied between 0 and 20% and adsorbent ratio between 15 and 25%. Automotive-used lubricating oil and industrial-used lubricating oil were treated using two different samples, acid and adsorbent. An increase in acid concentration showed a significant difference over the properties of oil such as density, viscosity, flash point, and other physiochemical properties nevertheless increasing the amount of acid over the optimum point made on significant change. Varying of adsorbent ratio showed little significant effect to density and flash point, while yield and viscosity were unaffected. Optimum point being at 10% acid and 25% adsorbent gave optimal result. All metal contaminants are substantially removed; total base number was improved, while increase in flash point suggested the method effectiveness. Treatment of used industrial oil was found to be easier to re-refine due to less contamination.